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Tiny tweaks for big wins in solar cells
by Staff Writers
Thuwal, Saudi Arabia (SPX) Aug 27, 2019

This sequence captures the fabrication process of a perovskite thin film from precursor solution to solid film via the spin-coating deposition process.

Solar cells that rely on perovskites to harvest sunlight are bound to gain in energy conversion efficiency thanks to an atomic-level understanding of the structure-property relationship of these photovoltaic materials. Researchers from the KAUST Solar Center monitored the impact of compositional changes on the structural organization and photovoltaic properties of perovskite thin films in situ1, 2.

Hybrid perovskites have emerged as key components in low-cost, high-efficiency solar cells because they are cheaper and easier to process than traditional silicon-based solar cell materials. In addition, they exhibit unique optoelectronic characteristics, including high light absorption and a defect tolerance that lead to solar cells with maximum power-conversion efficiencies of 24 to 28 percent when used alone or in tandem combination with silicon. They also outperform single-junction silicon solar cells.

Solar cell performance and stability depend on the morphology of the thin films, especially their ability to crystallize in the so-called photoactive a-phase. Perovskites containing lead tend to combine various halides, such as the anionic forms of bromine and iodine, with mixtures of methylammonium, formamidinium, cesium and other cations. These have led to record conversion efficiencies and thermal stabilities compared with their single-halide, single-cation analogs. However, these mixed-halide, mixed-cation perovskite films have been characterized only through ex-situ postdeposition techniques. This limits the understanding of the mechanisms that govern their growth from their sol-gel precursor to their solid state and stalls attempts to improve device performance and stability.

Now, Stefaan De Wolf, his postdoc Kai Wang and coworkers have investigated the impact of cations, halides and antisolvent dripping on mixed-halide, mixed-cation perovskite films. The team tracked the films' structural evolution during the spin-coating deposition process using an in situ X-ray scattering technique. The X-ray technique probed the films at the atomic scale from their sol-gel precursor to the solid state and provided information about the formation of crystalline intermediates during the solidification. The researchers also incorporated the films into solar cells and evaluated the performance and stability of the resulting devices.

"Our study provides critical insights into the crystallization of the multicomponent systems toward high-performance perovskite solar cells," Wang says. Changes in the compositions of the halide and cation dramatically affected the solidification of the perovskite precursors during spin coating and the subsequent formation of the desired a-phase upon antisolvent addition.

The period needed to generate high-quality films by antisolvent addition ended when the sol-gel structure collapsed to produce crystalline by-products depending on the precursor mixture. Consequently, tuning the halide-cation mixture could delay this collapse, widening the antisolvent dripping window from a few seconds to several minutes. As well, simultaneously incorporating cesium and rubidium cations in the perovskite synergistically stimulated the formation of the a-phase. The length of this window showed little effect on resulting solar cell performance as long as the antisolvent was added within this period.

These findings suggest new directions for the development of perovskite formulations that can further stabilize the sol-gel state and promote its conversion to the desirable perovskite phase. "This is critical in achieving better-performing, reproducible, cost-efficient and scalable manufacturing of perovskite solar cells," Wang says.

The team is working on transferring this knowledge to other deposition technologies to progress toward market-ready perovskite solar cells.

Research paper


Related Links
King Abdullah University of Science and Technology (KAUST)
All About Solar Energy at SolarDaily.com


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SOLAR DAILY
Materials that can revolutionize how light is harnessed for solar energy
New York NY (SPX) Aug 23, 2019
Researchers at Columbia University have developed a way to harness more power from singlet fission to increase the efficiency of solar cells, providing a tool to help push forward the development of next-generation devices. In a study published this month in Nature Chemistry, the team details the design of organic molecules that are capable of generating two excitons per photon of light, a process called singlet fission. The excitons are produced rapidly and can live for much longer than those gen ... read more

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